Material Safety Data Sheet
Product Code: UT-B-CL
Product Name: Urebond III-B
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Section 1: COMPANY IDENTIFICATION
RESIN TECHNOLOGY COMPANY
2270 CASTLE HARBOR PLACE
ONTARIO, CALIFORNIA 91761
Section 2: COMPOSITION/INFORMATION ON INGREDIENTS
Component / Exposure Limits - CAS# - % by Wt.
*
XYLENE (MIXED ISOMERS) 1330-20-7 33 XYLENE (MIXED ISOMERS), CAS# 1330-20-7, ACGIH TLV-100PPM TWA, STEL-150PPM, OSHA PEL-100PPM, STEL-150PPM. #TOLUENE CAS#108-88-3, 0.3-1.5%, ACGIH TLV-50 PPM TWA (SKIN), OSHA PEL-100 PPM TWA,STEL-150 PPM. NOTE: FLASH POINT MAY VARY FROM 80°F/26.7°C TO 76°F/24.4°C TCC DUE TO RAW MATERIAL VARIABLES. VAPOR PRESSURE IS 21MM HG @ 100°F/37.8°C. IPA, ISOPROPYL ALCOHOL, ISOPROPANOL-ANHYDROUS) 67-63-0 27 ACGIH TLV-400PPM TWA, STEL-500PPM. OSHA TLV-400PPM TWA, STEL-500PPM.
*
MODIFIED POLYAMIDE RESIN SOLUTION SOLUTION 25 30% XYLENE(MIXED), CAS# 1330-20-7, TLV-100PPM, STEL-150PPM. 8% MAX. 1-BUTANOL, CAS# 71-36-3, TLV-100PPM, STEL-50PPM.
*
ETHYLBENZENE 100-41-4 11 ETHYLBENZENE, CAS# 100-41-4, AGCHI: TLV-100PPM, STEL-125PPM. OSHA PEL-100PP M, STEL 125PPM.
*
N-BUTYL ALCOHOL, 1-BUTANOL, NORMAL BUTANOL. 71-36-3 4 1-BUTANOL, CAS#71-36-3, ACGIH TLV-50PPM CEILING, SKIN, OSHA PEL-50PPM CEILING, SKIN.
*
Indicates toxic chemical(s) subject to the reporting requirements of section 313 of Title III and of 40 CFR 372. THE HAZARDS OF BOTH PART A AND PART B WILL BE EXHIBITED WHEN BOTH PARTS ARE COMBINED. THIS MSDS MAY BE USED FOR OTHER COLORS AND CONTAINER SIZES OF THIS PRODUCT.
Section 3. HAZARDS IDENTIFICATION
Potential Health Effects
EYE AND SKIN: SKIN: THIS MATERIAL MAY CAUSE DEFATTING AND IRRITATION OF THE SKIN. PROLONGED OR REPEATED CONTACT MAY CAUSE DERMATITIS. EYES: THIS MATERIAL IS AN EYE IRRITANT.
INGESTION: MAY CAUSE MALAISE, HEADACHE, DISCOMFORT, BLEEDING OF GASTROINTESTINAL TRACT AND THE VOMITING OF BLOOD UNLESS TREATED PROMPTLY. DO NOT INDUCE VOMITING AND OBTAIN MEDICAL CARE AND HOSPITAL TREATMENT IMMEDIATELY.
INHALATION: VAPORS AND MISTS IRRITATE MUCOUS MEMBRANES. INHALATION OF HIGHER CONCENTRATIONS MAY CAUSE HEADACHES, NAUSEA, VOMITING AND COMA. INHALATION OF VERY HIGH CONCENTRATIONS OR PROLONGED EXPOSURE MAY CAUSE UNCONSCIOUSNESS OR DEATH.
Section 4. FIRST AID MEASURES
INHALATION: REMOVE TO FRESH AIR. GIVE ARTIFICIAL RESPIRATION IF NOT BREATHING. IF BREATHING IS DIFFICULT, ADMINISTER OXYGEN. TRAINED PERSONNEL ONLY SHOULD ADMINISTER OXYGEN. PREVENT ASPIRATION OF VOMIT. TURN VICTIMS HEAD TO THE SIDE. ASSURE OPEN AIRWAY. CALL A PHYSICIAN IMMEDIATELY.
EYES: HOLD EYELIDS APART AND IMMEDIATELY FLUSH WITH PLENTY OF WATER FOR AT LEAST 15 MINUTES. CONSULT A PHYSICIAN.
SKIN: REMOVE PRODUCT AND IMMEDIATELY FLUSH AFFECTED AREA WITH WATER FOR AT LEAST 15 MINUTES. EXCEPT IN THE MOST MINOR, SUPERFICIAL AND LOCALIZED BURNS, COVER THE AFFECTED AREA WITH A
STERILE DRESSING OR CLEAN SHEETING AND TRANSPORT FOR MEDICAL CARE. DO NOT APPLY GREASES OR OINTMENTS. CONTROL SHOCK IF PRESENT. DISCARD OR LAUNDER CONTAMINATED CLOTHING BEFORE REUSE. CONTAMINATED LEATHER WEAR SHOULD BE DISCARDED. INGESTION: IF SWALLOWED, DO NOT INDUCE VOMITING. ADMINISTER 3-4 GLASSES OF MILK OR WATER. OBTAIN MEDICAL CARE AND HOSPITAL TREATMENT IMMEDIATELY.
NOTE TO PHYSICIANS: INHALATION OF HIGH CONCENTRATIONS OF THIS MATERIAL, AS COULD OCCUR IN ENCLOSED SPACES OR DURING DELIBERATE ABUSE, MAY BE ASSOCIATD WITH CARDIAC ARRHYTHMIAS. SYMPTOMATIC DRUGS MAY INITIATE CARDIAC ARRHYTHMIAS IN PERSONS EXPOSED TO THIS MATERIAL. THIS MATERIAL IS AN ASPIRATION HAZARD. POTENTIAL DANGER FROM ASPIRATION MUST BE WEIGHED AGAINST POSSIBLE ORAL TOXICITY WHEN DECIDING WHETHER TO INDUCE VOMITING. PREEXISTING DISORDERS OF THE FOLLOWING ORGANS (OR ORGAN SYSTEMS) MAY BE AGGRAVATED BY EXPOSURE TO THIS MATERIAL: SKIN, LUNG(FOR EXAMPLE, ASTHMA-LIKE CONDITIONS), KIDNEY, AUDITORY SYSTEM, INDIVIDUALS WITH PREEXISTING HEART DISORDERS MAY BE MORE SUSCEPTIBLE TO ARRHYTHMIAS (IRREGULAR HEARTBEATS) IF EXPOSED TO HIGH CONCENTRATIONS OF THIS MATERIAL.
Section 5. FIRE FIGHTING MEASURES
FLAMMABLE PROPERTIES:
FLASH POINT: 52°F/-11°C TCC
FLAMMABLE LIMITS:
• Lower flammable limit: 1%
• Upper flammable limit: 12%@200°F
AUTOIGNITION TEMPERATURE: 980°F/526.6°C
EXTINGUISHING MEDIA: FOAM, CO2, DRY CHEMICAL, WATER FOG
FIREFIGHTING INSTRUCTIONS: DO NOT ENTER ANY ENCLOSED OR CONFINED FIRE SPACE WITHOUT FULL PROTECTIVE EQUIPMENT, INCLUDING SELF-CONTAINED BREATHING APPARATUS(PRESSURE-DEMAND MSHA/NIOSH APPROVED OR EQUIVALENT)TO PROTECT AGAINST THE HAZARDOUS EFFECTS OF COMBUSTION PRODUCTS AND OXYGEN DEFICIENCY. USE WATER SPRAY TO COOL FIRE EXPOSED CONTAINERS AND STRUCTURES. WATER, HOWEVER, MAY BE INEFFECTIVE FOR EXTINGUISHING FIRES.
Section 6. ACCIDENTAL RELEASE MEASURES
SMALL SPILL: ABSORB LIQUID WITH VERMICULITE, FLOOR ABSORBENT OR OTHER ABSORBENT MATERIAL AND TRANSFER TO DRUM. USE ONLY NON-SPARKING TOOLS.
LARGE SPILL: CLEAN UP PERSONNEL MUST BE EQUIPPED WITH SELF CONTAINED BREATHING APPARATUS AND BUTYL RUBBER PROTECTIVE CLOTHING. EVACUATE AREA OF ALL NON-ESSENTIAL PERSONNEL. EXTINGUISH ALL NEARBY SOURCES OF IGNITION AND VENTILATE AREA USING EXPLOSION PROOF MECHANICAL EXHAUST VENTILATION AS VAPORS ARE HEAVIER THAN AIR AND ARE COMBUSTIBLE OR FLAMMABLE AND MAY MIGRATE TO A SOURCE OF IGNITION. DIKE AND CONTAIN AND/OR ABSORB SPILL WITH INERT MATERIAL TO PREVENT ENTRY INTO STORM DRAINS, SEWERS AND OTHER UNAUTHORIZED TREATMENT/DRAINAGE SYSTEMS AND NATURAL WATERWAYS. COLLECT RUN-OFF WATER AND TRANSFER TO DRUMS OR TANKS FOR LATER DISPOSAL. USE ONLY NON-SPARKING TOOLS. IF SPILL OCCURS NEAR AIR INLETS OR INSIDE, TURN OFF HEATING OR AIR-CONDITIONING EQUIPMENT TO PREVENT CONTAMINATING BUILDING.
Section 7. HANDLING AND STORAGE
HANDLING: CONTAINERS, EVEN THOSE THAT HAVE BEEN EMPTIED, WILL RETAIN PRODUCT RESIDUE (LIQUID AND/OR VAPOR) AND CAN BE DANGEROUS. ALWAYS OBEY HAZARD WARNINGS AND HANDLE EMPTY CONTAINERS AS IF THEY WERE FULL. DO NOT PRESSURIZE, PUNCTURE, CUT, WELD, BRAZE, SOLDER, DRILL, GRIND, OR OTHERWISE
EXPOSE SUCH CONTAINERS TO HEAT, FLAME, SPARKS, STATIC ELECTRICAL CHARGES, ELECTRICITY, OR OTHER SOURCES OF IGNITION. THEY MAY EXPLODE AND/OR EMIT TOXIC VAPORS CAUSING INJURY OR DEATH. KEEP CONTAINER TIGHTLY CLOSED WHEN NOT IN USE. EMPTY CONTAINERS, ESPECIALLY DRUMS, SHOULD BE COMPLETELY DRAINED, PROPERLY BUNGED AND PROMPTLY RETURNED TO A DRUM RECONDITIONER, OR PROPERLY DISPOSED OF. CONCENTRATED VAPORS OF THIS PRODUCT ARE HEAVIER THAN AIR AND WILL COLLECT IN LOW AREAS SUCH AS PITS AND STORAGE TANKS AND OTHER CONFINED SPACES. CLOSED CONTAINERS MAY EXPLODE DUE TO PRESSURE BUILD-UP IF EXPOSED TO EXTREME HEAT. DO NOT GET IN EYES, ON SKIN OR ON CLOTHING. AVOID PROLONGED OR REPEATED BREATHING OF VAPOR OR SPRAY MIST. USE ONLY IN A WELL VENTILATED AREA. KEEP OUT OF THE REACH OF CHILDREN.
STORAGE: KEEP AWAY FROM HEAT, SPARKS, FLAME, AND OXIDIZERS. STORE IN A COOL, DRY, WELL-VENTILATED AREA AWAY FROM INCOMPATIBLE MATERIALS. AVOID BREATHING VAPORS. STORE IN CLOSED CONTAINERS, ABOVE GROUND SURROUNDED BY DIKES TO CONTAIN LEAKS OR SPILLS. VENT CONTAINERS IN WARM WEATHER TO
RELIEVE PRESSURE. ELECTRICALLY GROUND ALL EQUIPMENT WHEN HANDLING THIS PRODUCT AND USE ONLY NON-SPARKING TOOLS. DO NOT USE PRESSURE TO EMPTY CONTAINER. DO NOT GET IN EYES, ON SKIN OR ON CLOTHING.
Section 8. EXPOSURE CONTROLS/PERSONAL PROTECTION
ENGINEERING CONTROLS: IF CURRENT VENTILATION PRACTICES ARE NOT ADEQUATE DURING MIXING AND APPLICATION OPERATIONS TO MINIMIZE EXPOSURE, USE EXPLOSION-PROOF LOCAL EXHAUST VENTILATION CAPABLE OF MAINTAINING EMISSIONS AT THE POINT OF USE BELOW THE PEL OR TLV OR OTHER EXPOSURE GUIDELINES, AS APPROPRIATE. VENTILATION RATES SHOULD BE MATCHED TO CONDITIONS. EXPLOSION-PROOF MECHANICAL EXHAUST VENTILATION, WITH VOLUME AND PATTERN CAPABLE OF MAINTAINING A FRESH AIR SUPPLY, MAY BE NECESSARY IN CONFINED SPACES. REFER TO OSHA STANDARD 29 CFR 1910.94 FOR GUIDELINES. TURN OFF HEATING AND/OR AIR
CONDITIONING EQUIPMENT TO PREVENT CONTAMINATING BUILDING. IN OUTSIDE SPRAY APPLICATIONS, PROVIDE AIRFLOW IN A DOWNWIND DIRECTION SO AS TO CARRY FUMES AND RESIDUAL SPRAY AWAY FROM WORKERS.
RESPIRATORY PROTECTION: WEAR A NIOSH APPROVED RESPIRATOR APPROPRIATE FOR THE VAPOR OR MIST CONCENTRATION AT THE POINT OF USE. APPROPRIATE RESPIRATORS MAY BE A FULL FACEPIECE OR A HALF MASK AIR-PURIFYING CARTRIDGE RESPIRATOR EQUIPPED FOR ORGANIC VAPORS/MISTS, A SELF-CONTAINED BREATHING
APPARATUS IN THE PRESSURE DEMAND MODE, OR A SUPPLIED-AIR RESPIRATOR. REFER TO OSHA STANDARD 29 CFR 1910.134 FOR ADDITIONAL INFORMATION.
SKIN PROTECTION: THE USE OF GLOVES IMPERMEABLE TO THE SPECIFIC MATERIAL HANDLED IS ADVISED TO PREVENT SKIN CONTACT AND POSSIBLE IRRITATION. NOTE THAT PVA DEGRADES IN WATER.
EYE PROTECTION: CHEMICAL GOGGLES. IF SPLASHING MAY OCCUR OR DURING SPRAY OPERATIONS WEAR A FACE SHIELD, UNLESS A FULL FACE PIECE RESPIRATOR IS USED. DO NOT WEAR CONTACT LENSES AS THEY MAY CONTRIBUTE TO THE SEVERITY OF INJURY TO THE EYE FROM EXPOSURE TO LIQUID AND/OR VAPORS AND SPRAY MIST.
Section 9. PHYSICAL AND CHEMICAL PROPERTIES
| APPEARANCE: |
WATER THIN LIQUID. COLOR MAY VARY. |
| ODOR: |
AROMATIC ODOR |
| BOILING POINT: |
180°F/82.2°C |
| COATING V.O.C.: |
6.08 lb/gl |
| MELTING POINT: |
N/A |
| MATERIAL V.O.C.: |
6.08 lb/gl |
| VAPOR PRESSURE: |
5.10 MM HG@20°C |
| COATING V.O.C.: |
729 g/l |
| VAPOR DENSITY: |
HEAVIER THAN AIR |
| MATERIAL V.O.C. |
729 g/l |
| SOLUBILITY IN WATER: |
SLIGHTLY SOLUBLE. |
| pH: |
N/A |
| SPECIFIC GRAVITY: |
0.86 |
Section 10. STABILITY AND REACTIVITY
CHEMICAL STABILITY (CONDITIONS TO AVOID): STABLE
INCOMPATIBILITY: AVOID STRONG OXIDIZING AGENTS SUCH AS LIQUID CHLORINE, CONCENTRATED OXYGEN, SODIUM HYPOCHLORITE OR CALCIUM HYPOCHLORITE.
HAZARDOUS DECOMPOSITION PRODUCTS: THERMAL DECOMPOSITION MAY YIELD CARBON MONOXIDE, CARBON DIOXIDE AND NITROGEN COMPOUNDS. UNIDENTIFIED ORGANIC COMPOUNDS IN FUMES AND SMOKE MAY BE FORMED DURING COMBUSTION.
HAZARDOUS POLYMERIZATION: WILL NOT OCCUR.
Section 11. TOXICOLOGICAL INFORMATION
EYE: NO DATA.
SKIN: NO DATA.
INGESTION: TOXICITY DATA FOR MODIFIED POLYAMIDE RESIN SOLUTION.
ORAL: LD50 FOR RAT 4G/KG.
INHALATION: LC50 FOR MOUSE 3500PPM.TOXICITY DATA FOR MODIFIED POLYAMIDE RESIN SOLUTION.
SUBCHRONIC:ACUTE: EUPHORIA AND CENTRAL NERVOUS DEPRESSION, INCLUDING IMPAIRED MOTOR COORDINATION, SLURRED SPEECH, LOSS OF MUSCLE COORDINATION, STUPOR, AND COMA. DEATH MAY OCCUR DUE TO RESPIRATORY ARREST AND CONSEQUENT ASPHYXIA.
CHRONIC/CARCINOGENICITY: PROLONGED OR REPEATED EXPOSURE TO HIGH CONCENTRATIONS MAY CAUSE NEURAL DYSFUNCTION. LABORATORY ANIMALS EXPOSED TO HIGH DOSES OF XYLENE SHOWED EVIDENCE OF EFFECTS IN THE LIVER, KIDNEYS, LUNGS, SPLEEN, HEART AND ADRENALS. RATS EXPOSED DURING PREGNANCY SHOWED EMBRYO/FETOTOXIC EFFECTS. XYLENE HAS ALSO BEEN SUGGESTED TO CAUSE HEARING LOSS.
TERATOLOGY: XYLENE HAS BEEN SHOWN TO CAUSE BIRTH DEFECTS IN LABORATORY ANIMAL STUDIES. THE RELEVANCE OF THESE FINDINGS TO HUMANS IS UNCERTAIN.
REPRODUCTION: NO DATA.
MUTAGENICITY: NO DATA.
Section 12. ECOLOGICAL INFORMATION
ECOTOXICOLOGICAL INFORMATION: NO DATA.
CHEMICAL FATE INFORMATION: NO DATA.
Section 13. DISPOSAL CONSIDERATIONS
DISPOSE OF UNUSED PRODUCT OR CONTAMINATED PRODUCT AND MATERIALS USED IN CLEANING UP SPILLS OR LEAKS IN A MANNER APPROVED FOR THIS MATERIAL. CONSULT APPROPRIATE FEDERAL, STATE AND LOCAL REGULATORY AGENCIES TO ASCERTAIN PROPER DISPOSAL PROCEDURES. INCINERATION IS ACCEPTABLE AND THE PREFERRED METHOD OF DISPOSAL, HOWEVER; NITROGEN OXIDE EMISSIONS CONTROLS MAY BE REQUIRED TO MEET SPECIFICATIONS. CHEMICAL AND BIOLOGICAL DEGRADATION IS POSSIBLE.
Section 14. TRANSPORT INFORMATION
(Not meant to be all inclusive)
DOT INFORMATION: 49 CFR 172.101
DOT DESCRIPTION: COATING SOLUTION 3 UN 1139 II.
Section 15. REGULATORY INFORMATION
(Not meant to be all inclusive - selected regulations represented)
U.S. FEDERAL REGULATIONS:
STATUS OF SUBSTANCE LISTS: THE CONCENTRATIONS SHOWN IN SECTION II ARE MAXIMUM FOR CEILING LEVELS (WEIGHT %) TO BE USED FOR CALCULATIONS FOR REGULATIONS.
FEDERAL EPA: COMPREHENSIVE ENVIRONMENTAL RESPONSE, COMPENSATION AND LIABILITY ACT OF 1980 (CERCLA) REQUIRES NOTIFICATION OF THE NATIONAL RESPONSE CENTER OF RELEASE OF QUANTITIES OF HAZARDOUS SUBSTANCES EQUAL TO OR GREATER THAN THE REPORTABLE QUANTITIES (RQs) IN 40 CFR 302.4.
COMPONENTS PRESENT IN THIS PRODUCT AT A LEVEL THAT COULD REQUIRE REPORTING UNDER THE STATUTE ARE:
• XYLENE (MIXED ISOMERS) CAS #1330-20-7 RQ100#.
• ETHYL BENZENE CAS #100-41-4 RQ1000#.
• N-BUTYL ALCOHOL, (1-BUTANOL) CAS #71-36-3 RQ 5000#.
SUPERFUND AMENDMENTS AND REAUTHORIZATION ACT OF 1986 (SARA) TITLE III REQUIRES EMERGENCY PLANNING BASED ON THRESHOLD PLANNING QUANTITIES (TPQs) AND RELEASE REPORTING BASED ON REPORTABLE QUANTITIES (RQs) IN 40 CFR 355 (USED FOR SARA 302, 304, 311 AND 312).
COMPONENTS PRESENT IN THIS PRODUCT AT A LEVEL THAT COULD REQUIRE REPORTING UNDER THE STATUTE ARE:
• XYLENE(MIXED ISOMERS CAS#1330-20-7 RQ100#.
• ETHYLBENZENE CAS#100-41-4 RQ 1000#.
• N-BUTYL ALCOHOL (1-BUTANOL) CAS #71-36-3 RQ5000#.
REQUIRES SUBMISSION OF ANNUAL REPORTS OF RELEASE OF TOXIC CHEMICALS THAT APPEAR IN 40 CFR 372 (FOR SARA 313). THIS INFORMATION MUST BE INCLUDED IN ALL MSDSs THAT ARE COPIED AND DISTRIBUTED FOR THIS MATERIAL.
COMPONENTS PRESENT IN THIS PRODUCT AT A LEVEL THAT COULD REQUIRE REPORTING UNDER THE STATUTE ARE: SEE SECTION II.
TOXIC SUBSTANCES CONTROL ACT (TSCA) STATUS:
THE COMPONENTS OF THIS PRODUCT ARE LISTED OR ARE EXCLUDED FROM LISTING ON THE U.S. TOXIC SUBSTANCES CONTROL ACT (TSCA) CHEMICAL SUBSTANCE INVENTORY.
THE REMAINING PERCENTAGE OF UNSPECIFIED INGREDIENTS ARE NOT CONTAINED IN ABOVE de minimis CONCENTRATIONS AND/OR ARE BELIEVED TO BE NON-HAZARDOUS UNDER THE OSHA HAZARD COMMUNICATION STANDARD (29 CFR 1910.1200), AND MAY CONSIST OF PIGMENTS, FILLERS, DEFOAMERS, WETTING AGENTS, ANTI-BACTERIAL AGENTS, RESINS, DRYERS, WATER AND/OR SOLVENTS IN VARYING CONCENTRATIONS.
INTERNATIONAL REGULATIONS:
CANADIAN WHMIS: DSL (CANADA) THE INTENTIONAL INGREDIENTS OF THIS PRODUCT ARE LISTED. PRODUCT IS CLASSIFIED AS DIVISION 2 OF CLASS B- FLAMMABLE AND COMBUSTIBLE MATERIAL.
CANADIAN ENVIRONMENTAL PROTECTION ACT (CEPA): NO INFORMATION.
EINECS: NO INFORMATION.
STATE REGULATIONS:
STATE RIGHT TO KNOW:
CALIFORNIA PROPOSITION 65: BENZENE, CAS #71-43-2 (TRACE, LESS THAN 0.10%) FEBRUARY 27, 1987, KNOWN TO THE STATE OF CALIFORNIA TO CAUSE CANCER. THIS PRODUCT ALSO CONTAINS TOLUENE CAS#108-88-3, KNOWN TO THE STATE OF CALIFORNIA TO CAUSE REPRODUCTIVE HARM.
IN ADDITION TO THE ABOVE NAMED CHEMICALS, IF ANY, THIS PRODUCT MAY CONTAIN TRACE AMOUNTS OF SOME CHEMICALS CONSIDERED BY THE STATE OF CALIFORNIA TO BE CARCINOGENS OR REPRODUCTIVE TOXICANTS.
Section 16. OTHER INFORMATION
MSDS Status: THIS MSDS IS CURRENT AS OF MAY, 2000.
HMIS RATING: H F R P 3 3 0 J
THE INFORMATION CONTAINED HEREIN IS FURNISHED WITHOUT WARRANTY OF ANY KIND. USERS SHOULD CONSIDER THESE DATA ONLY AS A SUPPLEMENT TO OTHER INFORMATION GATHERED BY THEM & DETERMINE THE SUITABILITY & COMPLETENESS OF INFORMATION FROM ALL SOURCES TO ASSURE PROPER USE & DISPOSAL OF THESE MATERIALS & THE SAFETY & HEALTH OF EMPLOYEES & CUSTOMERS.
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