Material Safety Data Sheet
Section 1: Chemical Product and Company Identification
PRODUCT TRADE NAME: PERMAX® 700-B, PERMAX®-700-B-R, PERMAX®-700-B-R-S
PRODUCT DESCRIPTION: Elastomeric Coating
Date prepared or revised: 7/30/96
MANUFACTURER:
RESIN TECHNOLOGY COMPANY
2270 Castle Harbor Place
Ontario, CA 91761
(909) 947-7224
ADDITIONAL INFORMATION:
• James Doose - Resin Technology (909) 947-7224
• Monday - Friday 8:00 a.m. - 5:00 p.m. Pacific Time
• (800) 424-9300: CHEMTREC - Non-Business Hours Emergency Information Only.
Note: This product is a complex mixture and has not been tested as a whole. Information provided in this material safety data sheet is based on the limited knowledge Resin Technology Company has on the component parts of the mixture. Product composition ranges shown below are typical values for health, safety and environmental use and are not intended as specifications. See Section 16 for further information and explanation of abbreviations.
Section 2: Composition Information on Ingredients
| Item # |
Chemical Family and Hazardous Ingredients |
% W/W |
CAS |
ACGIH TLV |
OSHA PEL |
Other |
| Component 1: Jeffamine D-2000 |
Polyoxypropylenediamine mixture |
45-55% |
- |
- |
- |
- |
| - |
Poly(oxy(methyl-1,2-ethanediyl)), alpha-2( -aminomethylethyl)omega- (2-aminoethylethoxy) |
52% |
9046-10-0 |
None Established |
None Established |
- |
| Component 2: Baytec 505 |
Aromatic Diamine mixture |
20-30% |
- |
- |
- |
- |
| - |
2,6-Diethyltoluenediamine |
4.4 - 6.6% |
2095-01-4 |
None Established |
None Established |
- |
| - |
2,4-Diethyltoluenediamine |
15.4 - 17.6% |
2095-02-5 |
None Established |
None Established |
0.02 ppm |
| Component 3 De-60-F |
Pentabromodiphenyl Oxide and Aromatic Phosphate mixture |
5-15% |
- |
- |
- |
- |
| - |
Pentabromodiphenyl oxide |
>1% |
32534-81-9 |
None Established |
None Established |
- |
| - |
Tetrabromodiphenyl oxide |
>1% |
40088-47-9 |
None Established |
None Established |
- |
| - |
Aromatic phosphate NJ TSRN 80100076-5001P |
>1% |
- |
None Established |
None Established |
- |
| - |
Hexabromodiphenyl oxide |
>1% |
36483-60-0 |
None Established |
None Established |
- |
| - |
Tribromodiphenyl oxide |
>1% |
49690-94-0 |
None Established |
None Established |
- |
| Component 4 Sentry Pigment 1062 |
Titanium dioxide, Polyoxypropylenediamine mixture |
5-15% |
- |
- |
- |
- |
| - |
Titanium dioxide |
4.85% |
13463-67-7 |
10 mg/m3 (Total Dust) |
15 mg/m3 (Total Dust) |
- |
Section 3: Hazards Identification
EMERGENCY OVERVIEW
Nonflammable liquid (Flash point >300 °F) with Pungent Odor, and expected low volatility; Eye and Skin contact may cause burns or severe irritation; Inhalation may cause respiratory tract irritation; Harmful if swallowed.
HMIS: Health: 3, Flammability:1, Reactivity: 0
(0 = Minimal, 1 = Slight, 2 = Moderate, 3 = Serious, 4 = Severe)
POTENTIAL ROUTES OF ENTRY INCLUDE - Eye, Skin, Inhalation, and Ingestion.
• POTENTIAL HEALTH EFFECTS
• Eye: May cause chemical burn or severe irritation, experienced as pain, with excess blinking and tear production.
• Skin: Prolonged contact may be irritating to the skin or cause chemical burns. Overexposure to aromatic amines via skin absorption, may cause cyanosis, (purplish-blue color of the skin, lips and fingernails)
• Inhalation: apor or mist inhalation may be very irritating and may cause nasal discharge, coughing, and discomfort in nose and throat. Prolonged or repeated overexposure may result in lung damage. Material expected to have low volatility at normal room temperature therefore inhalation hazard increases when material is heated, sprayed, or used in poorly ventilated areas or confined spaces.
• Ingestion: Not a likely a significant route of exposure while following good work practices during normal industrial use. If a significant amount is ingested it may cause burning of mouth, throat, and stomach with abdominal and chest pain, nausea, vomiting, diarrhea, thirst, weakness, and collapse.
Cancer Information:
• None of the primary components are listed by NTP or IARC.
• None of the primary components are regulated OSHA carcinogens.
Medical Conditions Which May Be Aggravated:
Inhalation of vapors or mists may aggravate preexisting respiratory problems and skin contact may aggravate existing skin conditions.
Section 4: First Aid Measures
(See Section 11 Toxicology for information on toxicity and Notes to Physicians.)
EYE: Immediately flush eyes with plenty of water for at least 15 minutes. Hold eyelids apart while flushing to rinse entire surface of eye and eyelids with water. Do not attempt to neutralize with chemical agents. IF IRRITATION PERSISTS, IMMEDIATELY CONSULT WITH TRAINED MEDICAL PERSONNEL.
SKIN CONTACT: Immediately remove contamination from skin by washing with plenty of water. Remove contaminated clothing. Consult with trained medical personnel if irritation or other symptoms occur.
INHALATION: Move patient to fresh air. If breathing has stopped give artificial respiration. Get medical attention.
INGESTION: Should emergency first aid be required as a result of accidental ingestion, immediately consult with physician or poison control center and follow instructions of medical personnel.
Section 5: Fire Fighting Measures
Flammable Properties: Believed to be Non-Flammable
Flash Point: >300 °F Pensky-Martins closed Cup
Auto-ignition Temp: Not Tested
Lower Explosive Limit (LEL): Not Tested
Upper Explosive Limit (UEL): Not Tested
(Flammable Limits = Vol. % in air by ASTM-E)
Extinguishing Media: Use appropriate extinguishing media for surrounding fire:
Water Fog, Carbon Dioxide, Dry Chemical, Alcohol Foam
Fire Fighting Instructions: As with any fire, wear approved self-contained breathing apparatus in pressure demand mode and full protective gear.
Hazardous Combustion Products: Ammonia, oxides of nitrogen, oxides of carbon (CO2, CO), phosphorus and acidic vapors, aldehydes and ketones may be formed on burning in a limited air supply, possible hydrogen bromide and/or bromine, traces of hydrogen cyanide and other toxic gases. Unusual Fire And Explosion Hazards: Heat may increase pressure inside closed containers and cause them to rupture.
Section 6: Accidental Release Measures
SPECIFIC RECOMMENDATIONS: Follow standard industry practices for cleaning up chemical spills. There are no product specific techniques or recommendations for cleaning spills of this material.
GENERAL SPILL RESPONSE CONSIDERATIONS: Remove ignition sources. Stop leak if qualified and able to do so safely. Dike spill to prevent spreading into soil, sewage or other drainage systems, or bodies of water. Secure spill area. Open enclosed spaces to outside atmosphere. Be aware that vapors may tend to collect in low out of the way places.
Cover with inert material to absorb. Collect all contaminated material and place in container for proper disposal.
Always use proper personal protective equipment when cleaning-up spills.
Section 7: Handling and Storage
Practice reasonable care and caution in handling this material. Keep containers tightly closed. Store in a cool dry ventilated area. Protect from physical damage. Secondary containment is recommended for large volume storage to minimize impacts from an accidental release. Open containers carefully to allow any pressure build-up to vent safely. Do not get in eyes and avoid skin contact. Avoid breathing vapors. Read label before use.
Section 8: Exposure Controls/Personal Protection
Ventilation: Good general dilution ventilation matched to the conditions of product use is recommended to minimize potential exposures. Activities that generate aerosols are better controlled by local exhaust ventilation.
Respiratory Protection: Respiratory protection may be required to eliminate exposure to vapors or mist from this product when ventilation as described above is not provided. Should workplace conditions warrant the use of a respirator, ensure all requirements set forth under OSHA's 29 CFR 1910.134 on respiratory protection are met. A NIOSH/MSHA approved air purifying respirator with organic vapor cartridges may be appropriate under certain circumstances. Air supplied respirators should always be worn when airborne concentration of the contaminant or oxygen content is unknown.
Eye/Face Protection: Always wear chemical goggles, or safety glasses with side shields when working around this material. Use chemical goggles in conjunction with a protective face shield where splash or aerosol generation is anticipated
Skin Protection: Worker clothing should be appropriate for the risk of exposure. Any appropriate combination of chemical resistant clothing, whole body suites, aprons, gloves, and rubber boots should be appropriate to prevent hazardous skin contact.
Section 9: Physical and Chemical Properties
| Color: |
Pigmented |
| Vapor Pressure: |
Mixture Not Tested |
| Odor: |
Low Pungent Odor |
| Boiling Point: |
>300° F |
| Physical State: |
Liquid |
| Freezing/Melting point: |
Mixture Not Tested |
| pH: |
Mixture Not Tested |
| Solubility in Water: |
Mixture Not Tested |
| Vapor Density (air = 1): |
Mixture Not Tested |
| Specific Gravity: |
Mixture Not Tested |
Section 10: Stability and Reactivity
| Chemical Stability: |
Stable |
| Hazardous Polymerization: |
Will Not Occur |
| Conditions To Avoid: |
None Known |
| Incompatibility (with other materials): |
Strong Oxidizers, Strong Acids, Strong Bases |
| Hazardous Decomposition Products: |
Ammonia, oxides of nitrogen, oxides of carbon (CO2, CO), phosphorus and acidic vapors, irritating aldehydes and ketones may be formed on burning in a limited air supply, possible hydrogen bromide and/or bromine, traces of hydrogen cyanide. |
Section 11: Toxicology Information
Toxicological testing has not been performed on this product as a whole. The table below provides limited toxicity information on the individual components listed in Section 2.
| Sec. 2 Item # |
LD50 (Oral Toxicity) |
LC50 (Inhalation Toxicity) |
Skin |
Eye |
Other |
1:
Jeffamine D-2000 |
LD50(rat) = 0.48 g/kg |
No Data |
Dermal LD50 2.09 g/kg (rabbit); practically non toxic |
Extreme irritation (rabbit) |
None Given |
2:
Baytec 505 |
LD50(rat) = 472 mg/Kg |
LC50 (rat) -2.45 mg/L/1hr did not produce mortality |
Dermal LD50 >700 mg/Kg (rabbit) |
Moderate to severe irritation in rabbit eye |
Additional Data Available |
3:
De-60-F |
Pentabromo-diphenyl oxide: LD50(rat) 6200 mg/Kg
Aromatic Phosphate: Oral Toxicity >10 g/Kg (species not provided) |
Pentabromo-diphenyl oxide: Acute inhalation rats at 200 mg/L not toxic
Aromatic Phosphate: LC50 >200 mg/L |
Pentabromo-diphenyl oxide: Dermal LD50 >2000 mg/Kg (rabbit)
Aromatic Phosphate: Dermal Toxicity >10 g/Kg |
Slight eye irritant |
Pentabromo-diphenyl oxide: Acute hazard is eye irritation, Chronic hazard is liver damage
Aromatic Phosphate: May cause neurological disturbances. when ingested or inhaled in large quantities |
4:
Sentry Pigment 1062 |
Oral LD50(rat) > 7500 mg/kg |
No Data |
No Data |
No Data |
No Data |
Notes To Physician: No specific antidote. Supportive care treatment based on judgment in response to patient reactions.
Section 12: Ecological Information
No specific information available. A component of this mixture is reported to be highly toxic to aquatic life.
Section 13: Disposal Considerations
Disposal practice must be in compliance with local, state, and federal laws and regulations. Under the Resource Conservation and Recovery Act (RCRA), it is the responsibility of the user of the product to determine at the time of disposal, whether the product meets RCRA criteria for hazardous waste. Contact local and state environmental agencies for specific rules.
Section 14: Transportation Information
Amines, liquid, corrosive, n.o.s., 8, UN 2735, III
Section 15: Regulatory Information
The information provided below reflects information provided to Resin Technology Company on a few select regulations. This table is not meant to be all inclusive and users should ensure their activities comply with federal, state, and local laws and regulations.
| Sec. 2 Item # |
OSHA Haz. Com. Standard 29CFR 1910.1200 Hazardous Material |
California Proposition 65 Substances |
EPA TSCA Chemical Substances Inventory |
SARA 302 40 CFR Part 372 Extremely Hazardous |
SARA 313 40 CFR Part 372 (Toxic Chemicals) |
SARA 312 40 CFR 370 (Hazard Category) |
| 1 Jeffamine D-2000 |
Yes |
None |
Yes |
None |
None |
Acute |
| 2 Baytec 505 |
Yes |
Not Provided |
Yes |
None |
None |
Immediate Health |
| 3 De-60-F |
Yes |
Not Provided |
Yes |
Not Provided |
Not Provided |
Not Provided |
| 4 Sentry Pigment 1062 |
Yes |
Not Provided |
Yes |
None |
None |
Not Provided |
Section 16: Other
MSDS Preparation Notes:
Resin Technology Company is not aware of health effects studies or toxicology studies on the specific formulation of this product. Information provided in this MSDS about PERMAX-700B is based on the information provided to Resin Technology by the manufacturers of the component parts and other limited knowledge known to Resin Technology about the formulation. This product has not been tested as a whole.
The user is advised the exact formulation of PERMAX-700B is a trade secret of Resin Technology company. The criteria for listing components in Section 2 are based on the OSHA Hazard Communication Standard (HCS). A component is listed when present at ³ 1.0% of the total by weight and may be reported to meet the HCS definition of hazardous. Substances which meet the HCS criteria for posing a carcinogenic hazard are listed when present at ³ 0.1%.
Conditions of MSDS Use
The information contained herein is furnished in good faith but without warranty of any kind. This MSDS reflects information Resin Technology Company believes to be accurate on the date of preparation and is provided in accordance with the OSHA HCS. Users should consider these data a supplement to other information gathered by them and must make independent determination of suitability and completeness of information from all sources to ensure proper use, handling and disposal of this product. Users are solely responsible for handling, application, or other use of this product and for ensuring the safety and health of their employees and customers and the protection of the environment. Consult with Resin Technology Company if you need further information about this product.
Abbreviations:
ACGIH = American Conference of Governmental Industrial Hygienist
AIHA = American Industrial Hygiene Associatio
CAS = Chemical Abstract Service Registry Number
Governmental Industrial Hygienist;
EPA = U.S. Environmental Protection Agency
HCS = Hazard Communication Standard
HMIS = Hazardous Materials Information System
IARC = International Agency for Research on Cancer
LC50 = A calculated concentration of a material in air expected to kill 50 percent of a group of test animals
MSDS = Material Safety Data Sheet
MSHA = Mine Safety and Health Administration
NIOSH = National Institute for Occupational Safety and Health
NJTSRN = New Jersey Trade Secret Registration Number
NTP = National Toxicology Program
OEL = Occupational Exposure Level
OSHA = Occupational Safety and Health Administration
PEL = Permissible Exposure Limit
RCRA = Resource Conservation and Recovery Act
SARA = Superfund Amendments and Reauthorization Act
TLV = Threshold Limit Value
TSCA = Toxic Substances Control Act
WEEL = Workplace Environmental Exposure Level
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