Material Safety Data Sheet PRODUCT TRADE NAME(s): PERMAX-108, PERMAX-108-RH, PERMAX-108-FS, PERMAX-105,PERMAX-100, PERMAX-110, PERMAX-115 PRODUCT DESCRIPTION: Roof Mastic Coating DATE PREPARED: 12/1/94 (replaces 7/1/94) Revision Notes, Regulatory Information Update Changed 7/1/94 to 12/1/94 updated regulatory information on kadox (zinc ) and propylene oxide Note: This product has not been tested as a whole. Information provided in this material safety data sheet is based on the limited knowledge Resin Technology Company has on the component parts of the mixture. See Section 16 for further explanation. Section 1: COMPANY IDENTIFICATION MANUFACTURER'S NAME:    RESIN TECHNOLOGY COMPANY    2270 CASTLE HARBOR PLACE    ONTARIO, CALIFORNIA 91761 FOR ADDITIONAL INFORMATION: James Doose - Resin Technology (909) 947-7224 Monday - Friday 8:00 a.m. - 5:00 p.m. Pacific Time CHEMTREC - (800) 424-9300 - Non-Business Hours Emergency Information Only Section 2: Composition Information on Ingredients Item # Ingredients or Chemical Family % W/W CAS ACGIH TLV OSHA PEL Other Component 1 Rhoplex 1791 Acrylic Polymer with residual monomers in water 35-40 Mixture Not Established Not Established - Component 2 Alumina 432 Flame Retardant 30-35 21645-51-2 10 mg/m3 10 mg/m3 OEL -United Kingdom 2 mg/m3 Component 3 Kronos 2160 Titanium Dioxide 5-10 13463-67-7 10 mg/m3 15 mg/m3 (Transitional PEL) 10 mg/m3 (Final Rule) - Component 4 Kadox 915 Zinc Oxide 1-5 1314-13-2 10 mg/m3 10 mg/m3 - Component 5 Propylene glycol Propylene Glycol 1-3 57-55-6 Not Established Not Established AIHA WHEEL 50 ppm Component 6 Water 10-15 7732-18-5 Not Established Not Established - See Section 16 for explanation of abbreviations. Section 3: Hazards Identification EMERGENCY OVERVIEW: Pigmented Liquid; Nonflammable; Slight Odor; Eye and Skin contact may be irritating. Inhalation hazard generally considered low; Hazard from ingestion of a very small quantity is considered low. NFPA: Health: 1, Flammability: 0, Reactivity: 0 POTENTIAL ROUTES OF ENTRY INCLUDE - Eyes, Skin, Inhalation, and Ingestion. POTENTIAL HEALTH EFFECTS Eye: Direct contact to the eyes may be very irritating. Skin: Prolonged contact may be irritating to the skin. Inhalation: Vapors or mists may cause headache, nausea, and irritation of the nose throat and lungs. Ingestion: Should pose no significant hazard while following good work practices during normal industrial use. Cancer Information:    •   None of the primary components are listed by NTP or IARC.    •   None of the primary components are regulated OSHA carcinogens. Medical Conditions Which May Be Aggravated: Inhalation of vapors or mists may aggravate preexisting respiratory problems. Section 4: First Aid Measures (See Section 11 Toxicology for information on toxicity and Notes to Physicians.) EYE Immediately flush eyes with plenty of water for at least 15 minutes. Hold eyelids apart while flushing to rinse entire surface of eye and eyelids with water. IF IRRITATION PERSISTS, CONSULT WITH TRAINED MEDICAL PERSONNEL. SKIN CONTACT: Remove contamination from skin by washing with plenty of water. Remove contaminated clothing. Consult with trained medical personnel if irritation or other symptoms occur. INHALATION: In the event an exposure should occur, move patient to fresh air. If breathing has stopped give artificial respiration. Get medical attention. INGESTION: Should emergency first aid be required as a result of accidental ingestion, immediately consult with physician or poison control center and follow instructions of medical personnel. Section 5: Fire Fighting Measures Flammable Properties: Believed to be Non-Flammable Flash Point: Not Tested Auto-ignition Temp: Not Tested Lower Explosive Limit (LEL): Not Tested Upper Explosive Limit (UEL): Not Tested (Flammable Limits = Vol. % in air by ASTM-E) Extinguishing Media: Use appropriate extinguishing media for surrounding fire: Water Fog, Carbon Dioxide, Dry Chemical, Alcohol Foam Fire Fighting Instructions: As with any fire, wear approved self-contained breathing apparatus in pressure demand mode and full protective gear. Hazardous Combustion Products: None specifically known. Carbon monoxide and carbon dioxide anticipated. Unusual Fire And Explosion Hazards: Material may splatter at temperatures above 212°F. Pressure inside closed containers may increase in due to heat. Section 6: Accidental Release Measures SPECIFIC RECOMMENDATIONS: Follow standard industry practices for cleaning up chemical spills. There are no product specific techniques or recommendations known for cleaning spills of this material. GENERAL SPILL RESPONSE CONSIDERATIONS: Remove ignition sources. Stop leak if qualified and able to do so safely. Dike spill to prevent spreading into soil, sewage or other drainage systems, or bodies of water. Secure spill area. Open enclosed spaces to outside atmosphere. Be aware that vapors may tend to collect in low out of the way places. Cover with inert material to absorb. Collect all contaminated material and place in container for proper disposal. Always use proper personal protective equipment when cleaning-up spills. Section 7: Handling and Storage Practice reasonable care and caution in handling this material. Keep containers closed. Store in a cool dry ventilated area. Protect from physical damage. Secondary containment is recommended for large volume storage to minimize impacts from an accidental release. Open containers carefully to allow any pressure build-up to vent safely. Do not get in eyes and avoid skin contact. Avoid breathing vapors. Read label before use. Section 8: Exposure Controls/Personal Protection Ventilation: Good general dilution ventilation matched to the conditions of product use is recommended to minimize potential exposures. Activities that generate aerosols are better controlled by local exhaust ventilation. Respiratory Protection: Respiratory protection is not normally required for this product when ventilation is provided as described above. Should workplace conditions warrant the use of a respirator, ensure all requirements set forth under OSHA's 29CFR 1910.134 on respiratory protection are met. A NIOSH/MSHA approved air purifying respirator with ammonia or organic vapor cartridges may be appropriate under certain circumstances. A respiratory equiped with combination ammonia/organic vapor cartridge would be more sutitable when available. Eye/Face Protection: Wear chemical goggles or safety glasses with side shields. Where splash or aerosol generation is anticipated use goggles in conjunction with a fullface shield. Skin Protection: Worker clothing should be appropriate for the risk of exposure. Fabric coveralls and leather workgloves are recommended as minimum protection from skin contact. Section 9: Physical and Chemical Properties Color: Pigmented Vapor Pressure: No Data Odor: Low; Slight Acrylic Boiling Point: > 212 F Physical State: Liquid Freezing/Melting point: Not Available pH: No Data Solubility in Water: 100% Vapor Density (air = 1): > 1 Specific Gravity: 1.25 @ 20°C Section 10: Stability and Reactivity Chemical Stability: Stable Hazardous Polymerization: Will Not Occur Conditions To Avoid: None Known Incompatibility (with other materials): None Known Hazardous Decomposition Products: None Known Section 11: Toxicology Information Toxicological testing has not been performed on this product as a whole. The table below provides limited toxicological information on the individual ingredients listed in Section 2. Sec. 2 Item # LD50 Oral Rat LC50 Rat Skin Eye Other 1 Rhoplex 1791 Oral rat >5000 mg/kg No Data Dermal LD 50 >5000 mg/kg rabbit; practically non irritating rabbit Inconsequential irritation rabbit No Data 2 Alumina 432 No Data No Data No Data No Data Lowest Published Toxic Dose Human Child - 122 g/kg/4d 3 Kronos 2160 Oral rat >7700 mg/kg No Data No Data No Data No Data 4 Kadox 915 No Data No Data No Data No Data No Data 5 Propylene glycol Oral rat = 21 g/kg No Data Human irritant with possible toxic absorption and sensitization Transient redness rabbit; Stinging, redness, human No Data Notes to Physician: No specific antidote. Supportive care treatment based on judgment in response to patient reactions. Section 12: Ecological Information No specific information available. Section 13: Disposal Considerations Disposal practice must be in compliance with local, state, and federal laws and regulations. Under the Resource Conservation and Recovery Act (RCRA), it is the responsibility of the user of the product to determine at the time of disposal, whether the product meets RCRA criteria for hazardous waste. Contact local and state environmental agencies for specific rules. Section 14: Transportation Information Resin Compounds, 46030, Class 55, NOIBN, NON-HAZARDOUS Section 15: Regulatory Information The information provided below is not meant to be all inclusive. Information is provided about a few select regulations. Users should ensure their activities comply with federal, state, and local laws and regulations. Sec. 2 Item # OSHA Haz. Com. Standard 29CFR 1910.1200 Hazardous Material California Proposition 65 Substances EPA TSCA Chemical Substances Inventory SARA 302 40 CFR Part 355 (Ext. Hazardous) SARA 313 40 CFR Part 372 (Toxic Chemicals) SARA 312 40 CFR 370 (Hazard Category) 1 Rhoplex 1791 No No Data Yes No No None 2 Alumina 432 No No Data Yes No Data No Data No Data 3 Kronos 2160 No No Data Yes No Data No No Data 4 Kadox 915 Yes No Data Yes No Yes (contains zinc) Acute Chronic 5 Propylene glycol Yes No Yes No No Acute Chronic Section 16: Other MSDS Preparation Notes: Resin Technology Company is not aware of health effects studies or toxicology studies on the specific formulation of this product. Information provided in this MSDS about PERMAX®-108, PERMAX®-108-RH, PERMAX®-108-FS, PERMAX®-105, PERMAX®-100, PERMAX®-110 is based on the information provided to Resin Technology by the manufacturers of the component parts and other limited knowledge known to Resin Technology about the formulation. This product has not been tested as a whole. The user is advised the exact formulation of PERMAX®-108, PERMAX®-108-RH, PERMAX®-108-FS, PERMAX®-105, PERMAX®-100, PERMAX®-110 is a trade secret of Resin Technology Company. The criteria for listing components in Section 2 are based on the OSHA Hazard Communication Standard (HCS). A component is listed when present at3 1.0% of the total by weight and may be reported to meet the HCS definition of hazardous. Substances which meet the HCS criteria for posing a carcinogenic hazard are listed when present at3 0.1%. Conditions of MSDS Use: The information contained herein is furnished in good faith but without warranty of any kind. This MSDS reflects information Resin Technology Company believes to be accurate on the date of preparation and is provided in accordance with the OSHA HCS. Users should consider these data a supplement to other information gathered by them and must make independent determination of suitability and completeness of information from all sources to ensure proper use, handling and disposal of this product. Users are solely responsible for handling, application, or other use of this product and for ensuring the safety and health of their employees and customers and the protection of the environment. Consult with Resin Technology Company if you need for further information about this product. Abbreviations: ACGIH = American Conference of Governmental Industrial Hygienist AIHA = American Industrial Hygiene Associatio CAS = Chemical Abstract Service Registry Number Governmental Industrial Hygienist; EPA = U.S. Environmental Protection Agency HCS = Hazard Communication Standard HMIS = Hazardous Materials Information System IARC = International Agency for Research on Cancer LC50 = A calculated concentration of a material in air expected to kill 50 percent of a group of test animals MSDS = Material Safety Data Sheet MSHA = Mine Safety and Health Administration NIOSH = National Institute for Occupational Safety and Health NJTSRN = New Jersey Trade Secret Registration Number NTP = National Toxicology Program OEL = Occupational Exposure Level OSHA = Occupational Safety and Health Administration PEL = Permissible Exposure Limit RCRA = Resource Conservation and Recovery Act SARA = Superfund Amendments and Reauthorization Act TLV = Threshold Limit Value TSCA = Toxic Substances Control Act WEEL = Workplace Environmental Exposure Level VOC Calculation for PERMAX®: VOC = Total Weight of Volatiles-Weight of Water Total Volume – Volume of water = (Batch weight – Weight of Non-volatile) – Weight of water Batch volume – Volume of water = (3030# - 1961.55#) - 1015.45# 275 gal - 122.05 gal = .346#/gal = (.346#) 454gm 3.785 liters / gal = 41 gm/liter


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